Author:
Raalte D. Van,Harrison A. G.
Abstract
The reactions leading to formation of the hydronium ion in the mass spectra of a number of alcohols and formate esters have been elucidated through a study of appearance potentials and metastable transitions and by the use of deuterium labelling. The results lead to ΔHf(H3O+) = 157 ± 3 kcal/mole corresponding to a proton affinity of the gaseous water molecule of 151 ± 3 kcal/mole.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
74 articles.
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