THE FREEZING POINTS OF HIGH PURITY METALS AS PRECISION TEMPERATURE STANDARDS: IV. INDIUM: THERMAL ANALYSES ON THREE GRADES OF CADMIUM

Abstract

An investigation of the freezing and melting temperatures of a sample of high purity indium (Cominco 99.999+ %) has been made. Plateaux of essentially constant (< ± 0.0001 °C) temperature with durations for over 1 hour are readily obtained on the cooling curves of induced freezes on this metal. The standard deviation of the plateau temperature (liquidus point) from a series of 24 induced freezes was ±0.0001 °C. The pressure effect on the freezing temperature of indium was found to be 0.0049 °C for 1 atm. Alloy melting ranges were measured following different types of freezing.An extensive intercomparison of liquidus points and alloy melting ranges has been made on a sample of 99.99% cadmium and two samples of 99.999+ % cadmium from different suppliers. The liquidus points of the high purity samples were indistinguishable using precision resistance thermometry but one sample melted over a slightly smaller range of temperature than the other. Both these samples showed minor arrests on melting curves after induced freezing and detailed analyses of the melting contours after various types of freezing indicated some evidence of characteristic structure inside a range of 0.002 °C.