Author:
Cohen Robert L.,Sisti Anthony J.
Abstract
A number of 1-(2-aminophenyl)-1-(substituted aryl)ethanols were deaminated, yielding ketones, formed by a molecular rearrangement and, in some instances, azo ketones formed by intramolecular coupling and cleavage. The sensitivities of these two reactions, one characteristic of the aryl cation and the other of the diazonium group, to relatively small changes in the electrical nature of the migrating group were determined.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
7 articles.
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