Abstract
Evidence is presented which indicates that for Ni2+ in lanthanum magnesium double nitrate the zero field splitting of the ground state has not been adequately accounted for. Better agreement between theory and experiment is obtained by allowing a partial breakdown of Russell–Saunders coupling. The deduced deviation from the Landé interval rule depends significantly on the covalency contribution to the zero field splitting.
Publisher
Canadian Science Publishing
Subject
General Physics and Astronomy
Cited by
2 articles.
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