Flash vacuum pyrolysis of anthracenic Diels–Alder adducts, a convenient source of methanethial and methanethial S-oxide-Reference-Cited by-同舟云学术

Flash vacuum pyrolysis of anthracenic Diels–Alder adducts, a convenient source of methanethial and methanethial S-oxide

Published:1987-02-01 Issue:2 Volume:65 Page:290-291
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Vallee Yannick,Ripoll Jean-Louis,Lafon Christophe,Pfister-Guillouzo Geneviève

Abstract

The flash vacuum pyrolysis of Diels–Alder adducts of anthracene constitutes a rapid and selective route to methanethial 1 and methanethial S-oxide 2, as analyzed in the gas phase by photoelectron spectroscopy. Low temperature infrared and nuclear magnetic resonance (1H, 13C) spectra are also reported for sulfine 2.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v87-047

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