Author:
Agarwala U.,Rees C. E.,Thode H. G.
Abstract
The sulfur isotope effects in the decomposition of tri-, tetra-, and penta-thionate have been studied. There are three distinct intermolecular and three distinct intramolecular isotope effects. The experimental results show that the decomposition of these polythionates may be described in terms of a model where the rate-controlling step is the cleavage of a sulfur–sulfur bond, and that the appropriate cleavage forms are (S2O32−) (SO3), (S3O3) (SO32−), and (S4O3) (SO32−) for tri-, tetra-, and penta-thionate, respectively.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
3 articles.
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