On the synthesis of cryptosporiopsin: stereochemistry of early intermediates
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Published:1982-08-15
Issue:16
Volume:60
Page:2062-2064
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ISSN:0008-4042
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Container-title:Canadian Journal of Chemistry
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language:en
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Short-container-title:Can. J. Chem.
Author:
Strunz George M.,White Peter S.
Abstract
The relative configurations of two intermediates in the synthetic route to cryptosporiopsin are clarified through the structure of 3,5-dichloro-1,4-dihydroxy-2-methylcyclopent-2-ene-1-carboxylic acid methyl ester, which was determined by single crystal X-ray techniques. The crystal was monoclinic, space group P21/c, a = 7.352(1), b = 8.868 (3), c = 16.300(7) Å; β = 96.49(2)°. The structure was solved by direct methods and refined to a final R of 0.057.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis