Palladium chloride catalyzed photochemical Heck reaction-Reference-Cited by-同舟云学术

Palladium chloride catalyzed photochemical Heck reaction

Published:2013-05 Issue:5 Volume:91 Page:348-351
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Waghmode Suresh B.¹,Arbuj Sudhir S.¹,Wani Bina N.²,Gopinath C.S.³

Affiliation:

1. Department of Chemistry, University of Pune, Ganeshkhind, Pune-411007, India.

2. Chemistry Division, Bhabha Atomic Research Centre, Mumbai-400085, India.

3. Catalysis Division, National Chemical Laboratory, Pune-411008, India.

Abstract

PdCl2 catalyzed carbon–carbon bond formation (Heck reaction) between substituted aryl halides and olefins was carried out without a ligand, under irradiation with UV–visible light. The results demonstrated that UV–visible light accelerated the rate of the reaction, leading to an excellent yield of corresponding products. The recovered palladium nanoparticles could be thermally recycled several times. PdCl2 gave excellent conversion up to the fifth addition of substrate.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2012-0377

Reference62 articles.

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2. bTsuji, J. Palladium Reagents and Catalysis; Wiley. Chiehester, 1995;

3. Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides

4. The Asymmetric Intramolecular Heck Reaction in Natural Product Total Synthesis

5. The Heck Reaction as a Sharpening Stone of Palladium Catalysis

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