Author:
Singh Surjit,Rao C. N. R.
Abstract
The interaction of phenol and phenol-d with a number of donors of varying basicity has been studied in terms of the equilibrium constants, ΔS0, ΔH0, ΔvOH, and ΔvOD and various aspects of deuterium isotope effects on hydrogen bonding have been discussed. The deuterium isotope effects are found to vary markedly with the basicity of the donor and the results are discussed in terms of the zero point contributions to the KH/KD.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
51 articles.
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