Author:
Rogers I. H.,Manville J. F.
Abstract
The petroleum ether extract from the whole-wood meal of a British Columbia Interior variety of Douglas-fir has yielded a new and potentially useful juvenile hormone mimic, (−)-cis-4-[1′(R)-5′-dimethyl-3′-oxohexyl]-cyclohexane-1-carboxylic acid (3a). This compound possesses the opposite steric configuration at C-1′ to that of (+)-juvabione (1a), which has been isolated by others from balsam fir. Also, it occurs exclusively as the free acid. Not all Douglas-firs contain this compound and the biological consequences of its formation are being explored.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
16 articles.
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