SYNTHESES AND POLYMERIZATION OF α-TRIMETHYLSILYL ACRYLIC MONOMERS-Reference-Cited by-同舟云学术

SYNTHESES AND POLYMERIZATION OF α-TRIMETHYLSILYL ACRYLIC MONOMERS

Published:1963-12-01 Issue:12 Volume:41 Page:2977-2982
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Ottolenghi Ariel,Fridkin Mati,Zilkha A.

Abstract

α-Trimethylsilyl acrylic acid and its methyl ester were prepared in good yield starting from 1,2-dibromoethyltrimethylsilane. These monomers were polymerized with difficulty by free radicals to viscous polymers, but gave solid copolymers with styrene. The methyl ester was also a weak monomer in anionic polymerization. This non-reactivity is due to the steric effect of the α-trimethylsilyl group adjacent to the double bond.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v63-437

Reference8 articles.

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4. THE ADDITION OF ORGANOLITHIUM COMPOUNDS TO VINYLTRIPHENYL- AND VINYLTRIMETHYL-SILANES

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