Abstract
Reactions of Cu(I)Cl, Cu(II)Cl2, Cu(II) acetylacetonates, and Cu(II) N-methylsalicylalidiiminate with the stable free radical 2,2-diphenyl-1-picrylhydrazyl have been investigated. In all cases Cu(II) was reduced and the organic radical behaved as an electron donor-ligand to form complexes containing Cu(I). These novel free radical Cu(I) complexes were characterized by various spectroscopic methods, including e.s.r.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
8 articles.
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