Author:
Darwish David,Scott Christopher E.
Abstract
The rate constants for racemization by inversion of a variety of monoaryl- and diarylsulfonium salts are reported. There is a marked steric effect upon the rate of the racemization reaction. An estimate is made of the half-life for racemization of acyclic optically active triarylsulfonium salts.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
24 articles.
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