Author:
Gumulka Maria,Ibrahim Ibrahim Halim,Bończa-Tomaszewski Zbigniew,Engel Ch. R.
Abstract
An efficient synthesis from adrenosterone or 11α-hydroxytestosterone of 17β-hydroxy-11-aza-5α-androstan-3-one, the 11-aza analogue of dihydrotestosterone, is described. For the elaboration of the 11-aza structure, a pathway implying a Curtius-type rearrangement of a 9,11-seco 9-oxo 11-acid was employed.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
23 articles.
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