Author:
Kutney Gerald W.,Still Ian W. J.
Abstract
The reactions of a series of N,N′-dialkyl and N,N′-diaryl malondiamides with disulfur dichloride have been reinvestigated. The claim, made almost 60 years ago. that the products of this reaction are dithioketones R2CS2, is shown to be unfounded. The structures of these products are shown to be the symmetrically substituted 1,2,4,5-tetrathianes, 8a–e.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
20 articles.
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3. Chapter 4 Sulfur Monochloride in the Synthesis of Heterocyclic Compounds;Advances in Heterocyclic Chemistry;2008
4. Novel conversion of 6H-1,3,5-oxathiazineS-oxides into 3H-1,2,4-dithiazoles by treating with Lawesson's reagent;Heteroatom Chemistry;2004
5. Formation, Structure, and Thionation of 1,2,4,5-Tetrathianes [cis- andtrans-3,6-Bis(1,1,3,3-tetramethyl-4-oxo-4-phenylbutyl)-1,2,4,5-tetrathianes];Bulletin of the Chemical Society of Japan;2000-03