Enantioselective fluorescent sensors for chiral carboxylates based on BINOL — Synthesis and chiral recognition-Reference-Cited by-同舟云学术

Enantioselective fluorescent sensors for chiral carboxylates based on BINOL — Synthesis and chiral recognition

Published:2010-04 Issue:4 Volume:88 Page:367-374
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Xu Kuo-xi¹²,Wang Yu-xia¹²,Jiao Shu-yan¹²,Zhao Jin¹²,Wang Chao-jie¹²

Affiliation:

1. College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China.

2. Key Lab of Natural Medicinal and Immunal Engineering, Henan University, Kaifeng 475004, China.

Abstract

The four novel derivatives of 1,1′-bi-2-naphthol (BINOL) have been prepared, and the structures of these compounds have been characterized by IR, MS, 1H and 13C NMR spectroscopy, and elemental analysis. The enantioselective recognition of these receptors has been studied by fluorescence titration and 1H NMR spectroscopy. The receptors exhibited different chiral-recognition abilities towards some enantiomers of chiral materials and formed 1:1 complexes between host and guest. The receptors exhibit excellent enantioselective fluorescent-recognition ability towards the amino acid derivatives.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/V10-001

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