Author:
Stojanac Žarko,Dickinson Robert A.,Stojanac Nada,Woznow Ronald J.,Valenta Zdenek
Abstract
Lewis acid catalysts cause an orientation reversal in the Diels–Alder additions of 2,6-di-methyl-1,4-quinone (1) and toluquinone (12) to 1-substituted 1,3-butadienes and to 1,2- and 1,3-dialkyl dienes. These results are explained by the preferential formation of one reactive quinone–Lewis acid salt.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
71 articles.
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