APPLICATION OF THE VIBRATIONAL SUM RULE TO HALOGENATED ETHYLENES

Author:

Bernstein H. J.

Abstract

The vibrational sum rule has been applied to the fluoro-chloro-bromo-ethylenes and good agreement obtained between observed frequency sums and those calculated on the basis of additivity considerations. Two unobserved frequencies for trans dibromoethylene have been calculated and the in-plane and out-of-plane sums for some molecules not yet investigated. Several ambiguities with regard to some halogenated ethylenes have been resolved and several assignments which merit reinvestigation have been indicated.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Reference2 articles.

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