Author:
McKeown G. G.,Hayward L. D.
Abstract
A pyridine solution of dulcitol hexanitrate evolved gas and became highly colored when warmed to 50 °C.; dilution with water caused the precipitation of 67% of the theoretical amount of a dulcitol pentanitrate. The product was characterized as D,L-galactitol-1,2,4,5,6-pentanitrate by methylation to a monomethyl dulcitol pentanitrate, denitration of the latter, and periodate oxidation of the monomethyl dulcitol obtained. The hexitol derivatives were all obtained in a pure crystalline form. The significance of the data now available on the selective partial denitration by pyridine of hexitol hexanitrates is briefly discussed.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
15 articles.
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