Abstract
Finely divided spruce wood was heated with aqueous sodium bicarbonate and excess carbon dioxide up to 160° and about 400 p.s.i. in attempts to carboxylate the lignin according to the Kolbe–Schmitt method and to extract the product as a soluble sodium salt. Only small amounts of lignin were removed, together with larger amounts of the holocellulose. Heating the wood with anhydrous liquid ammonia up to 100° and about 900 p.s.i. extracted only small amounts of material from the softwood spruce, but 25 to 30% of the lignin was removed from the hard woods beech, birch, and maple and 52% from rye straw. The solution of ammonium chloride or sodium cyanide in the liquid ammonia increased these percentages substantially, and also the concomitant extraction of holocellulose.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
11 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献