Abstract
Chlorination of propyne at 70 °C. gave 60 to 65% yields of 1,1,2,2-tetrachloropropane and 15 to 20% yields of trans-1,2-dichloro-1-propene. 1,1,2,2-Tetrachloropropane-d4 was similarly prepared from propyne-d4. Nearly theoretical yields of cis- and trans-1,2-dichloro-1-propene were obtained by partial dechlorination of tetrachloropropane. Deuterated cis- and trans-1,2-dichloro-1-propene were obtained in the same manner from 1,1,2,2-tetrachloropropane-d4.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
14 articles.
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