Author:
Burton Gordon R.,Chan Wing Fat,Cooper Glyn,Brion C. E.,Kumar Ashok,Meath William J.
Abstract
Newly available and highly accurate oscillator strength data, extending over the continuous energy range from the first excitation threshold to 200 eV, are used together with mixture rule estimates and other photoabsorption data to construct a refined dipole oscillator strength distribution to infinite photon energy using Thomas–Reiche–Kuhn sum rule and molar refractivity constraints. This constrained dipole oscillator strength distribution has been used to calculate a wide range of related dipole properties (Sk, k = 2, 1, 0, −1/2, −1, −3/2, −2, −5/2, −3, −4, −5, −6, −8, −10, −12; Lk and Ik, k = 2, 1, 0, −1, −2). The theoretical analysis and associated consistency checks support the high accuracy of the newly available absolute oscillator strengths for the photoabsorption of NH3.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
31 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献