Author:
Dutton G. G. S.,Briggs T. I.,Brown B. R.,Hillman M. E. D.
Abstract
Amine salts of dinitroalkyl phenols have been suggested as herbicides and insecticides. A selection of such amine salts was examined as to their suitability for characterizing dinitroalkyl phenols. The following new salts are described: the piperidine, morpholine, and cyclohexylamine salts of each of 2,4-dinitrophenol, 4,6-dinitro-2-methylphenol, 2,6-dinitro-4-methylphenol, 4,6-dinitro-2-isopropylphenol, 2,6-dinitro-4-isopropyl phenol, 4,6-dinitro-2-(sec-butyl)-phenol, 2,6-dinitro-4-(tert-butyl)-phenol, and 2,6-dinitro-4-(tert-amyl)-phenol. In addition, the preparation of 4,6-dinitro-2-isopropylphenol and 2,6-dinitro-4-isopropylphenol does not appear to have been previously described. The use of these salts, and similar ones with other amines, is recommended for the preparation of crystalline derivatives of dinitrophenols.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
15 articles.
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