Author:
Orejón Aránzazu,Castellanos Aída,Salagre Pilar,Castillón Sergio,Claver Carmen
Abstract
New neutral cobalt(II) complexes containing 2,9-bis(2-hydroxyphenyl)-1,10-phenanthroline and 2,9-bis(2-hydroxyphenyl)-2,2′-bipyridine ligands have been synthesized. These complexes are active catalysts in the oxidative carbonylation of aniline in 1-butanol and NaI as a promoter. The principal products obtained are N,N′-diphenylurea and 1-butyl-N-phenylcarbamate.Key words: cobalt, oxidative carbonylation, aniline, N,N′-diphenylurea, 1-butyl-N-phenylcarbamate.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
13 articles.
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