THE ANALYSIS OF NUCLEAR MAGNETIC RESONANCE SPECTRA: III. PYRIDINE AND DEUTERATED PYRIDINES

Author:

Schneider W. G.,Bernstein H. J.,Pople J. A.

Abstract

The proton resonance spectra of pyridine, 2,6-pyridine-d2, 3-pyridine-d1, and 4-pyridine-d1 have been obtained for the pure liquids under conditions of high resolution. The spectra have been analyzed as proton groupings of AB2X2, AB2, perturbed ABX, and B2X2 respectively. The spin-coupling constants obtained from analysis of the simpler spectra of the deuterated molecules were used to suggest trial solutions for the analysis of the complicated AB2X2 spectrum of pyridine. A final set of chemical shifts and spin-coupling constants derived for pyridine give satisfactory agreement between the observed and calculated spectrum.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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