Abstract
The microwave spectrum of 1,3-dioxane has been studied within the region 8 to 40 GHz. The rotational constants of the molecule in its ground vibrational state are, in MHz, A = 4999.94(0.05), B = 4807.61 (0.05), and C = 2757.12(0.05). The dipole moment components are, in Debye units, μb = 1.61 (0.02), μc = 1.29(0.01), and μ = 2.06(0.03). The values of the above quantities are consistent with a chair form structure. Rotational spectra due to five excited vibrational states of 1,3-dioxane have been assigned.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
30 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Mixing states of imidazolium-based ionic liquid, [C4mim][TFSI], with cycloethers studied by SANS, IR, and NMR experiments and MD simulations;Physical Chemistry Chemical Physics;2020
2. Structure and spectra of 1,3-dioxanes. microwave spectrum, structural parameters, and ab initio calculations of 5-methyl-1,3-dioxane;Journal of Structural Chemistry;2010-04
3. Stereoelectronic Effects on the Conformational Properties of 1,3-Dioxane, 1,3-Dithiane, and 1,3-Diselenane: An Ab Initio Study and NBO Analysis;Phosphorus, Sulfur, and Silicon and the Related Elements;2008-09-15
4. Microwave spectrum, centrifugal perturbation, dipole moment, and conformation of 5-methyl-1,3-dioxane;Journal of Structural Chemistry;2008-07
5. Structure and spectra of 1,3-dioxanes. II. Microwave spectrum, structural parameters, and ab initio calculations of 2-methyl-1,3-dioxane;Journal of Structural Chemistry;2007-11