An improved one-pot cost-effective synthesis of N,N-disubstituted carbamoyl halides and derivatives-Reference-Cited by-同舟云学术

An improved one-pot cost-effective synthesis of N,N-disubstituted carbamoyl halides and derivatives

Published:2010-12 Issue:12 Volume:88 Page:1277-1280
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Adeppa K.¹²,Rupainwar D. C.¹²,Misra Krishna¹²

Affiliation:

1. U.P. Technical University, Lucknow (U.P.)-226000, India.

2. Indian Institute of Information Technology, Allahabad (U.P.)-211002, India.

Abstract

A convenient one-pot procedure is reported for preparing N,N-disubstituted carbamoyl chlorides by using chlorocarbonylsulfenyl chloride as a carbonylating agent. It comprises the reaction of secondary amines with chlorocarbonylsulfenyl chloride in the presence of an aprotic organic solvent to produce the corresponding N,N-disubstituted carbamoyl halides. Insertion of the carbonyl group without using phosgene is the novelty of this method.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/V10-138

Reference17 articles.

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