Author:
Gillespie R. J.,Kapoor R.,Robinson E. A.
Abstract
It is shown that a number of phosphates ionize in sulfuric acid to give the P(OH)4+ion. Triphenyl phosphine and triethyl phosphate are fully protonated but phosphorus oxyfluoride and phosphorus oxychloride are shown to be nonelectrolytes.Ammonium metavanadate and vanadium pentoxide give the acid H[VO(HSO4)4] and there is evidence that the dimer H[V2O3(HSO4)6] and possibly higher polymers are present in increasing amounts with increasing concentration.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
37 articles.
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