A DOUBLE MAGNETIC FIELD MODULATION PARAMAGNETIC RESONANCE SPECTROMETER

Author:

Buckmaster H. A.,Scovil H. E. D.

Abstract

A high sensitivity, wide or narrow band, double magnetic field modulation type paramagnetic resonance spectrometer operating at a wavelength of 1.25 cm. for use at liquid helium temperatures (4 °K.) is described. The spectrometer employs a transmission type, cylindrical resonant cavity excited in the H111 mode. The magnetic field is modulated simultaneously at 60 c.p.s. and 465 kc. A resonance from 10−11 mole of diphenyl trinitro phenyl hydrazyl has been observed with a signal-to-noise ratio of 2:1 at 290 °K. in wide band operation (8 kc.) indicating that a sensitivity of O(10−15) mole should be possible in narrow band operation (1 c.p.s.) at 4 °K. because of its inherent high stability.

Publisher

Canadian Science Publishing

Subject

General Physics and Astronomy

Cited by 17 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Spectrometers;Multifrequency Electron Paramagnetic Resonance;2011-04-21

2. Measurement Methods and Instruments for Microwave Frequencies;Encyclopedia of Physics / Handbuch der Physik;1967

3. A spiral resonator for an electron paramagnetic resonance spectrometer with high frequency modulation of the magnetic field;Cryogenics;1964-06

4. Methods of Measurement;Electron Paramagnetic Resonance;1964

5. Electron Spin Resonance in Semiconductors;Solid State Physics;1962

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