Abstract
A least-squares method is described for calculating compositions of equilibrium solid phases from data on solubilities and either wet residues or initial compositions for systems of three or more thermodynamic components. The method minimizes the squares of areas of triangles formed by the solubility, wet residue (or initial composition), and solid composition points. Full descriptions of error analyses and hypothesis tests are given, along with an illustrative example and detailed comparisons with the traditional extrapolation method.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
11 articles.
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