Reaction of RuO4 with KrF2: A clear-cut method to prepare ruthenium oxide tetrafluoride-Reference-Cited by-同舟云学术

Reaction of RuO4 with KrF2: A clear-cut method to prepare ruthenium oxide tetrafluoride

Published:1989-11-01 Issue:11 Volume:67 Page:1729-1731
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Meublat Laurent,Lance Monique,Bougon Roland

Abstract

The fluorination of ruthenium tetroxide RuO4 was attempted by using either fluorine or krypton difluoride KrF2 in HF solution. Of the two fluorinating agents, only KrF2 was found to be powerful enough to react with RuO4 and to transform it into ruthenium oxide tetrafluoride RuOF4. This oxide fluoride of ruthenium VI was characterized by elemental analysis, X-ray powder diffraction, and infrared absorption spectroscopy. Keywords: ruthenium tetroxide, ruthenium oxide tetrafluoride, krypton difluoride, fluorination.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v89-266

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