Aromatic substitution. XV. The homolytic methylation of pyridine and 3- and 4-picoline-Reference-Cited by-同舟云学术

Aromatic substitution. XV. The homolytic methylation of pyridine and 3- and 4-picoline

Published:1967-03-01 Issue:5 Volume:45 Page:509-513
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Abramovitch R. A.,Kenaschuk K.

Abstract

The ratios of isomers formed in the free-radical methylation of pyridine and 3- and 4-picoline have been determined and the results compared with the corresponding phenylations. The results support the concept that methyl radicals are more nucleophilic than phenyl radicals.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v67-086

Reference9 articles.

1. AROMATIC SUBSTITUTION: XIV. THE HOMOLYTIC PHENYLATION OF 3- AND 4-PICOLINE. A QUANTITATIVE STUDY OF ISOMER AND TOTAL RATE RATIOS

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