Dipole moments of substituted chloroformates in dilute benzene solutions

Author:

Bock E.,Iwacha D.

Abstract

The dipole moments of methyl, ethyl, n-propyl, n-butyl, amyl, and phenyl chloroformate as well as n-butyl formate in dilute benzene solution at 25 °C were determined. The experimental results suggest that the configuration of the chloro-esters differs from the configuration of the unchloroinated esters, viz. the ester hydrocarbon group and the chlorine atom are cis to each other.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 28 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Dipole Moments of Compounds Containing Double Bonds;PATAI'S Chemistry of Functional Groups;2009-12-15

2. Correlation of the rates of solvolysis of phenyl chloroformate;Journal of the Chemical Society, Perkin Transactions 2;1997

3. A microwave and ab initio structure determination of methyl chloroformate;Chemical Physics;1990-04

4. Polarity, polarizability, and structure of esters. 6. Conformations of para-substituted phenyl chloroformates in solutions;Bulletin of the Academy of Sciences of the USSR Division of Chemical Science;1989-12

5. Conformation and electronic structure of aromatic chloroformates;Collection of Czechoslovak Chemical Communications;1987

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