Author:
Piers Edward,Britton Ronald W.,Waal William de
Abstract
A novel and efficient total synthesis of the racemic form of the sesquiterpene (−)-aristolone (1) is presented. The key step involves the cupric sulfate catalyzed intramolecular cyclization of the diazoketone 27, which produces a mixture of products, the major component of which is (±)-aristolone.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
55 articles.
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