Substituted ferrocenecarboxylic acids and esters-Reference-Cited by-同舟云学术

Substituted ferrocenecarboxylic acids and esters

Published:1990-05-01 Issue:5 Volume:68 Page:705-707
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Cullen W. R.,Wickenheiser E. B.

Abstract

The synthesis of Fe(η-C5H5)(η-C5H3(CHMeNMe2)(COOH)-1,2), 3a, and its methyl and ethyl esters is described. Esterification of 3a by using RI in DMA affords Fe(η-C5H5)(η-C5H3(CHMeOH)(COOR)-1,2), R = Me, Et, with retention of configuration at the chiral center. The variable temperature 1H NMR spectrum of 3a reveals H-bonding between the two functional groups. Keywords: ferrocenecarboxylic acids and esters, NMR spectra, synthesis, hydrogen bonding.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v90-109

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