Author:
Bellas M. G.,Strausz O. P.,Gunning H. E.
Abstract
The reaction was studied in a circulatory apparatus under a variety of conditions. The sole primary process occurring is C—Cl bond scission. The Cl atoms formed in the primary step, through an abstractive attack on the substrate, generate chlorodifluoromethyl radicals (CF2Cl) All principal reaction products, CF2H2, CF2Cl2, CF2ClCF2Cl, CF2HCF2H, and CF2HCF2Cl, can be accounted for by the combination–disproportionation reactions of the CF2H• and CF2Cl• radicals. The observed strong dependence of the primary quantum yields on the incident light intensities has been ascribed to a rapid substrate-reforming step.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
20 articles.
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