Catalytic hypervalent iodine oxidation of alcohols to the corresponding carbonyl compounds usingN-hydroxyphthalimide (NHPI) andm-chloroperbenzoic acid-Reference-Cited by-同舟云学术

Catalytic hypervalent iodine oxidation of alcohols to the corresponding carbonyl compounds usingN-hydroxyphthalimide (NHPI) andm-chloroperbenzoic acid

Published:2010-04 Issue:4 Volume:88 Page:362-366
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Zhu Chenjie¹,Ji Lei¹,Zhang Qian¹,Wei Yunyang¹

Affiliation:

1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.

Abstract

An efficient, facile, and mild oxidation of alcohols to the corresponding carbonyl compounds with m-chloroperbenzoic acid (mCPBA) and N-hydroxyphthalimide (NHPI) in the presence of a catalytic amount of iodobenzene was reported. The oxidation proceeded in mixed solvent at room temperature to afford carbonyl compounds in excellent yields. A possible mechanism for the oxidation was proposed.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/V10-007

Reference54 articles.

1. (a) Tojo, G.; Fernández, M.Oxidation of Primary Alcohols to Carboxylic Acids;Springer: Berlin, 2006;

2. (b) Tojo, G.; Fernández, M.Oxidation of Alcohols to Aldehydes and Ketones;Springer: Berlin, 2006;

3. Large-Scale Oxidations in the Pharmaceutical Industry

4. (a) Varvoglis, A.Hypervalent Iodine in Organic Chemistry;Academic Press: London, 1997;

5. Organic Polyvalent Iodine Compounds

Cited by 16 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Fabrication of Copper-doped Porous NiO Heterogeneous Catalyst and Its Application in Aerobic Oxidation of Benzyl Alcohol;CHEM J CHINESE U;2023

2. Electrochemical alcohols oxidation mediated by N-hydroxyphthalimide on nickel foam surface;Scientific Reports;2020-11-09

3. Formation of Aldehydes and Ketones by Oxidation;Comprehensive Organic Transformations;2018-02-28

4. Bis(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with O2 under metal- and base-free conditions;Green Chemistry;2018

5. Iodobenzene-Catalyzed Ortho-Dearomatization and Aromatization-Triggered Rearrangement of 2-Allylanilines: Construction of Indolin-3-ylmethanols with High Diastereoselectivities;Organic Letters;2017-12-01