Author:
Demchuk Nick,Gesser H. D.
Abstract
The gas phase reaction of hydrogen atoms with carbon suboxide was studied over the temperature range of−96 to 235 °C and was found to proceed via a chain reaction. The products found were CH4, CO, CH2CO, C2H6, (CHO)2, and polymer. A mechanism is proposed and the chain reaction is explained by the intermediate formation of ketene and the formyl radical.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
4 articles.
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