Organoantimony compounds. I. Infrared spectra of some trimethyl- and triphenyl-antimony derivatives

Author:

Goel R. G.,Joshi P. N.,Ridley D. R.,Beaumont R. E.

Abstract

Organoantimony compounds of the type R3SbX and (R3Sb)2OX, where R is methyl or phenyl, and X is a bivalent anionic group such as SeO4, CrO4, or C2O4, have been prepared. Structural characteristics of these compounds have been determined by studying their infrared spectra in the solid state between 4000 and 250 cm−1. The spectral results indicate that in both types of compounds the anion X is coordinated to the R3Sb or (R3Sb—O—SbR3) group resulting in non-ionic, five coordinate, polymeric structures.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 22 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Tris[triphenylantimony(V)]hexa(μ-oxido)tellurium(VI): a molecular complex with six Te—O—Sb bridges;Acta Crystallographica Section E Crystallographic Communications;2021-11-04

2. References;Vibrational Spectra of Organometallics;2018-12-07

3. References;Vibrational Spectra of Organometallics;2018-12-07

4. Antimony: Annual survey covering the year 1992;Journal of Organometallic Chemistry;1994-09

5. Phenylantimony(V) oxalates: isolation and crystal structures of [SbPh4][SbPh2(ox)2], [SbPh3(OMe)]2ox and (SbPh4)2ox;Journal of the Chemical Society, Dalton Transactions;1992

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