Author:
He Xiao-Feng,Vogels Christopher M,Decken Andreas,Westcott Stephen A
Abstract
Oxidative cyclization of 2-aminothiophenol, 2-aminophenol, and 1,2-phenylenediamine with 2-thiophenecarboxaldehyde affords the corresponding 2-thiophen-2-ylbenzothiazole, -benzoxazole, and -benzimidazole compounds. Addition of these ligands (L) to [PtCl2(coe)]2 (coe = cis-cyclooctene) gives complexes of the type trans-PtCl2L(coe) in moderate yields. Crystals of the benzothiazole derivative (1) were monoclinic, space group P2(1)/c, a = 11.561(4) Å, b = 15.335(15) Å, c = 11.769(4) Å, β = 105.182(5)°, Z = 4.Key words: platinum, imine, benzothiazole, benzoxazole, benzimidazole.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
8 articles.
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