The detection of ruthenium chloride clusters by laser desorption ionization-mass spectrometry of RuCl3·3H2O

Author:

Boncheff Alexander G.1,Monteiro Mario A.1

Affiliation:

1. Department of Chemistry, University of Guelph, Guelph, ON N1G 2W1, Canada.

Abstract

The production of gas-phase singly charged ruthenium chloride anionic complexes by laser desorption ionization of RuCl3·3H2O is reported. The [RuxCly] clusters could only be detected in the absence of the matrix component in the negative mode. The cluster compositions observed were [RuCl4], [RuCl5], [Ru2Cl6], [Ru2Cl7], [Ru3Cl9], [Ru4Cl11], and [Ru5Cl12]. With the aid of density functional theory calculations, we proposed feasible structures for each ruthenium chloride cluster, in which Ru–Ru bonds and Cl bridges were a common characteristic.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Reference13 articles.

1. Carbohydrate-Metal ComplexesCarbohydrate–metal complexes : Structural Chemistry of Stable Solution Species

2. Transition-metal saccharide chemistry: synthesis, spectroscopy, electrochemistry and magnetic susceptibility studies of iron(III) complexes of mono- and disaccharides

3. Metal chelation by the common 2-amino-2-deoxy-, 2-N-acetylamino-2-deoxy-, and 2-deoxy-hexoses

4. A Sugar's Choice:  Coordination to a Mononuclear or a Dinuclear Copper(II) Complex?

5. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Mennucci, B.; Petersson, G. A.; Nakatsuji, H.; Caricato, M.; Li, X.; Hratchian, H. P.; Izmaylov, A. F.; Bloino, J.; Zheng, G.; Sonnenberg, J. L.; Hada, M.; Ehara, M.; Toyota, K.; Fukuda, R.; Hasegawa, J.; Ishida, M.; Nakajima, T.; Honda, Y.; Kitao, O.; Nakai, H.; Vreven, T.; Montgomery, J. A., Jr.; Peralta, J. E.; Ogliaro, F.; Bearpark, M.; Heyd, J. J.; Brothers, E.; Kudin, K. N.; Staroverov, V. N.; Kobayashi, R.; Normand, J.; Raghavachari, K.; Rendell, A.; Burant, J. C.; Iyengar, S. S.; Tomasi, J.; Cossi, M.; Rega, N.; Millam, J. M.; Klene, M.; Knox, J. E.; Cross, J. B.; Bakken, V.; Adamo, C.; Jaramillo, J.; Gomperts, R.; Stratmann, R. E.; Yazyev, O.; Austin, A. J.; Cammi, R.; Pomelli, C.; Ochterski, J. W.; Martin, R. L.; Morokuma, K.; Zakrzewski, V. G.; Voth, G. A.; Salvador, P.; Dannenberg, J. J.; Dapprich, S.; Daniels, A. D.; Farkas, O.; Foresman, J. B.; Ortiz, J. V.; Cioslowski, J.; Fox, D. J. Gaussian 09, Revision A.02; Gaussian, Inc.: Wallingford, CT, 2009.

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3