Author:
Arnold S. J.,Kimbell G. H.,Snelling D. R.
Abstract
Infrared chemiluminescence from vibrationally excited CO was observed when CH3Cl, CH2Cl2, CHCl3, or CH2Br2 was introduced into a stream of oxygen atoms. Emission from vibrationally excited HCl was also observed from CH2Cl2 and CHCl3. The mechanisms describing the reactions of oxygen atoms with these molecules are discussed in detail. The reaction step responsible for the formation of CO† is postulated to be[Formula: see text]and for HCl†[Formula: see text]
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
8 articles.
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