Author:
Chambers R. D.,Clark H. C.,Willis C. J.
Abstract
A methyl group is cleaved by chlorine in preference to trifluoromethyl from trimethyltrifluoromethyltin and dimethyltrifluoromethyltin chloride; the significance of this is discussed in terms of the electronegativity of the trifluoromethyl group. The influence of trifluoromethyl on the acceptor properties of the tin atom in dimethyltrifluoromethyltin chloride has been illustrated by means of conductivity measurements. Nuclear magnetic resonance measurements of trimethyltrifluoromethyltin and dimethyltrifluoromethyltin chloride are also reported.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
18 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Cleavage of the Tin-Carbon Bond;Inorganic Reactions and Methods;2007-05-29
2. Novel Perfluoroalkyl-Diphenylphosphine Compounds. Syntheses and Reaction Mechanisms;Organometallics;2004-05-05
3. Trimethyl(trifluoromethyl)stannane;Encyclopedia of Reagents for Organic Synthesis;2001-04-15
4. 2 Hydrogen-1 NMR. References;Chemical Shifts and Coupling Constants for Hydrogen-1. Part 4;2001
5. 2 Hydrogen-1 NMR. Chemical shift. Substance no. 1ff;Chemical Shifts and Coupling Constants for Hydrogen-1. Part 4;2001