PREPARATION AND CHEMISTRY OF Δ8-HEXAHYDRO-1,4,8-PYRIMIDAZOLE, Δ9-1,5,9-TRIAZABICYCLO(4.4.0)DECENE, AND Δ9-1,4,9-TRIAZABICYGLO(5.3.0)DECENE

Author:

Mckay A. F.,Kreling M.-E.

Abstract

The preparations of Δ8-hexahydro-1,4,8-pyrimidazole, Δ9-1,5,9-triazabicyclo(4.4.0)decene, and Δ9-1,4,9-triazabicyclo(5.3.0)decene from the corresponding 2-(ω-hydroxyalkylamino)-Δ2-1,3-diazacycloalkenes by chlorination and dehydrohalogenation are described. The nitro derivatives of these bicyclic compounds are more stable towards refluxing ethanol than 1-nitro-2,3,5,6-tetrahydro-1-imidaz(1,2-a)imidazole.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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