Author:
Kelly Ronald B.,Harley Mary Lou,Alward Sandra J.
Abstract
A total synthesis of (±)-stemarin, a diterpenoid with a unique C/D ring System, is described. The synthesis features photoaddition of allene to an α,β-unsaturated ketone and two skeletal rearrangements. Application of the synthetic strategy described herein to a synthesis of stemodinol and aphidicolin is anticipated.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
41 articles.
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