Author:
Barthez Jean M,Filikov Anton V,Frederiksen Lottie B,Huguet Marie-Loire,Jones John R,Lu Shui-Yu
Abstract
The benefits of using microwaves to accelerate the rates of hydrogen isotope exchange reactions are illustrated by reference to heterogeneous and homogeneous metal-catalysed reactions as well as to homogeneous acid-catalysed reactions. The results show that good incorporation of deuterium is obtained in very short time intervals, typically <20 min, and that the approach has considerable potential for the labeling of a wide range of compounds with both deuterium and, by implication, tritium.Key words: microwave enhanced deuteriations, hydrogen isotope exchange.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
21 articles.
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