The syntheses and properties of C-silylimines and their thermal rearrangements to N-silylenamines-Reference-Cited by-同舟云学术

The syntheses and properties of C-silylimines and their thermal rearrangements to N-silylenamines

Published:1978-09-01 Issue:17 Volume:56 Page:2286-2291
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Brook Adrian G.,Golino Carlo,Matern Eberhard

Abstract

C-Silylimines have been synthesized by silylation of lithioaldimines prepared from isonitriles. Their ultraviolet and C=N infrared absorptions show bathochromic shifts relative to related aldimines or ketimines and the nmr spectra show the presence of syn–anti isomers, probably due to nitrogen inversion. The silylimines undergo intramolecular thermal rearrangements at about 200–235 °C yielding N-silylenamines, which have been characterized.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v78-377

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