Author:
Buchanan Gerald W.,Ozubko Richard S.
Abstract
13C n.m.r. signal assignments are presented for the carcinogenic polynuclear hydrocarbon benzo[a]pyrene. In addition to selective 1H decoupling, valuable information is obtained from the magnitudes of the α-, β-, and "peri" deuterium isotope shifts in the 1,3,6-trideuterio analog. The applicability of the model compound approach to signal assignment is explored in detail.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
26 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Human‐ and computer‐accessible 2D correlation data for a more reliable structure determination of organic compounds. Future roles of researchers, software developers, spectrometer managers, journal editors, reviewers, publisher and database managers toward artificial‐intelligence analysis of NMR spectra;Magnetic Resonance in Chemistry;2016-10-02
2. Reduction of Benzo[A]Pyrene in Coal Tar Pitch with Cross Linking Monomers;Advanced Materials Research;2013-02
3. First Examples of Fluorinated and Chlorinated Polycyclic Aromatic Hydrocarbon (PAH) Dications from Benzo[a]pyrene, Pyrene, and Their Alkyl-Substituted Derivatives;The Journal of Organic Chemistry;1998-10-16
4. Benzo[a]pyrene in coal tar pitch: chemical conversion in situ by alkylation;Fuel;1996-10
5. Synthesis and NMR characterization of a dioxa-analog of benzo[a]pyrene: The 1-benzopyrano[6,5,4-mna]-xanthene (1,6-dioxabenzo[a]pyrene);Journal of Heterocyclic Chemistry;1995-01