Author:
Maneshkarimi M.,Heydtmann H.
Abstract
Infrared chemiluminescence from the product molecule HF (DF) was observed for the F + CH4(CD4) and F + CHCl3 reactions under low-pressure flow conditions. The reactions with methane and deuterated methane showed the well-known vibrational inversion effect. For the mixed reaction situation F + CH4(CD4) + CHCl3 it can be shown by switching between CH4 and CD4 that no special relaxation effects are present. The HF (DF) spectra can be explained by results from the isolated reactions. A non-inverted distribution was confirmed for F + CHCl3.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
7 articles.
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