Author:
Chung Fine Man,Westland Alan D.
Abstract
Enthalpies of addition were determined calorimetrically for the crystalline complexes MX4•2L where M = Zr or Hf, X = Cl or Br, and L = tetrahydrofuran or tetrahydrothiophene. With oxygen as the donor atom of L, the two metalhalides exhibited nearly identical acceptor power but with sulfur as donor, HfCl4 proved to be the better acceptor. Hafnium(IV) shows more class b character than zirconium(IV).
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
24 articles.
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